The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prismatic [Co6N(CO)15]-, contains a large metallic cluster formed by two superimposed rather folded centered-hexagons of cobalt atoms, with three interstitial nitrogen atoms located at the centres of three non adjacent distorted trigonal prismatic cavities. © 1988.

A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3 / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 358:1-3(1988), pp. C23-C23-C25.

A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3

G. Ciani;A. Sironi
1988

Abstract

The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prismatic [Co6N(CO)15]-, contains a large metallic cluster formed by two superimposed rather folded centered-hexagons of cobalt atoms, with three interstitial nitrogen atoms located at the centres of three non adjacent distorted trigonal prismatic cavities. © 1988.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/188056
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