The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prismatic [Co6N(CO)15]-, contains a large metallic cluster formed by two superimposed rather folded centered-hexagons of cobalt atoms, with three interstitial nitrogen atoms located at the centres of three non adjacent distorted trigonal prismatic cavities. © 1988.
A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3 / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 358:1-3(1988), pp. C23-C23-C25.
A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3
G. CianiSecondo
;A. SironiUltimo
1988
Abstract
The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prismatic [Co6N(CO)15]-, contains a large metallic cluster formed by two superimposed rather folded centered-hexagons of cobalt atoms, with three interstitial nitrogen atoms located at the centres of three non adjacent distorted trigonal prismatic cavities. © 1988.
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