The first chemical example of "la coupe du roi", i.e., the bisection of an achiral molecule into homochiral halves, has been achieved by a reaction sequence that transforms cis-3,7-dimethyl-1,5-cyclooctanedione (C20 symmetry) into 2-methyl-1,4-butanediol (C1 symmetry). © 1988 American Chemical Society.
Bisection of an achiral molecule into homochiral halves: The first chemical analogue of "la coupe du roi" / M. Cinquini, F. Cozzi, F. Sannicolò, A. Sironi. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 110:13(1988), pp. 4363-4364. [10.1021/ja00221a041]
Bisection of an achiral molecule into homochiral halves: The first chemical analogue of "la coupe du roi"
M. Cinquini;F. Cozzi;F. Sannicolò;A. Sironi
1988
Abstract
The first chemical example of "la coupe du roi", i.e., the bisection of an achiral molecule into homochiral halves, has been achieved by a reaction sequence that transforms cis-3,7-dimethyl-1,5-cyclooctanedione (C20 symmetry) into 2-methyl-1,4-butanediol (C1 symmetry). © 1988 American Chemical Society.
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