The use of water instead of benzene as the solvent can strongly influence the stereoselectivity and the rate of Diels-Alder reactions of 1,4-naphthoquinone derivatives with different dienes. Enantiomeric excess (e.e.) up to 38% is reached in the presence of a catalytic amount of bovine serum albumin.

CHANGES OF STEREOSELECTIVITY AND RATE IN DIELS-ALDER REACTIONS BY HYDROPHOBIC SOLVENT EFFECTS AND BY BOVINE SERUM-ALBUMIN / S. COLONNA, A. MANFREDI, R. ANNUNZIATA. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 29:27(1988), pp. 3347-3350.

CHANGES OF STEREOSELECTIVITY AND RATE IN DIELS-ALDER REACTIONS BY HYDROPHOBIC SOLVENT EFFECTS AND BY BOVINE SERUM-ALBUMIN

A. MANFREDI
Secondo
;
R. ANNUNZIATA
Ultimo
1988

Abstract

The use of water instead of benzene as the solvent can strongly influence the stereoselectivity and the rate of Diels-Alder reactions of 1,4-naphthoquinone derivatives with different dienes. Enantiomeric excess (e.e.) up to 38% is reached in the presence of a catalytic amount of bovine serum albumin.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/187819
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