More than 98 % of A.I. is obtained during addition of TosMic with chiral complexes 2 and 3. The diastereoselectivity of the formation of the oxazolines is studied and the diastereomers clearly assigned. Orbital-interactions and electronic repulsions seem to be responsable for the presence of the cis isomers.

ARENE-CHROMIUM-TRICARBONYL COMPLEXES - STEREOSELECTIVE REACTIONS WITH ISOCYANIDE / A. SOLLADIE-CAVALLO, S. QUAZZOTTI, S. COLONNA, A. MANFREDI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 30:22(1989), pp. 2933-2936.

ARENE-CHROMIUM-TRICARBONYL COMPLEXES - STEREOSELECTIVE REACTIONS WITH ISOCYANIDE

A. MANFREDI
Ultimo
1989

Abstract

More than 98 % of A.I. is obtained during addition of TosMic with chiral complexes 2 and 3. The diastereoselectivity of the formation of the oxazolines is studied and the diastereomers clearly assigned. Orbital-interactions and electronic repulsions seem to be responsable for the presence of the cis isomers.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/187756
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