The cross coupling reaction promoted by [V2Cl3(THF)6]2[Zn2Cl6] of some aliphatic aldehydes with an aromatic aldehyde bearing a chiral auxiliary occurs in a stereocontrolled fashion to give syn 1,2- diols in diastereoisomeric ratios up to 91:9 and enantiomeric excesses up to 84%.

Vanadium II promoted diastereo- and enantioselective intermolecular pinacol cross coupling / R. Annunziata, M. Cinquini, F. Cozzi, P. Giaroni. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 1:6(1990), pp. 355-358. [10.1016/0957-4166(90)90032-6]

Vanadium II promoted diastereo- and enantioselective intermolecular pinacol cross coupling

R. Annunziata
Primo
;
M. Cinquini
Secondo
;
F. Cozzi
Penultimo
;
1990

Abstract

The cross coupling reaction promoted by [V2Cl3(THF)6]2[Zn2Cl6] of some aliphatic aldehydes with an aromatic aldehyde bearing a chiral auxiliary occurs in a stereocontrolled fashion to give syn 1,2- diols in diastereoisomeric ratios up to 91:9 and enantiomeric excesses up to 84%.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/187751
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