Low temperature meta-chloroperbenzoic acid oxidation of allylic sulphide derived from (1S)-10-mercaptoisoborneol proceeds in a completely diastereoselective fashion to afford a configurationally stable allylic sulphoxide. The factors affecting the selectivity of the oxidation and the optical stability of the product are discussed.

Synthesis of configurationally stable allylic sulphoxides via diastereoselective oxydation / R. Annunziata, M. Cinquini, F. Cozzi, S. Farina, V. Montanari. - In: TETRAHEDRON. - ISSN 0040-4020. - 43:5(1987), pp. 1013-1018.

Synthesis of configurationally stable allylic sulphoxides via diastereoselective oxydation

R. Annunziata
Primo
;
M. Cinquini
Secondo
;
F. Cozzi;
1987

Abstract

Low temperature meta-chloroperbenzoic acid oxidation of allylic sulphide derived from (1S)-10-mercaptoisoborneol proceeds in a completely diastereoselective fashion to afford a configurationally stable allylic sulphoxide. The factors affecting the selectivity of the oxidation and the optical stability of the product are discussed.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/187713
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