Nitrilimine cycloadditions onto a variety of alkenyl dipolarophiles were performed for the first time in aqueous media. The observed cycloaddition outcome was markedly dependent on several factors, including the electronic features and the solubility in water of the dipolarophiles, as well as the presence of a cationic surfactant or an organic cosolvent in the reaction mixture.
|Titolo:||Nitrilimine cycloadditions in aqueous media|
|Parole Chiave:||Diels-alder reactions; organic-reactions; 1,3-dipolar cycloadditions; water; reactivity; oxide; dipolarophiles; heterocycles; solvent; carbon|
|Settore Scientifico Disciplinare:||Settore CHIM/06 - Chimica Organica|
|Data di pubblicazione:||2000|
|Digital Object Identifier (DOI):||10.1039/b005567k|
|Appare nelle tipologie:||01 - Articolo su periodico|