The luminescent receptor 1 incorporating anthracenyl groups as luminophores and a tetraoxa-tetraaza macrobicyclic receptor as the binding subunit has been synthesized and its interactions with Ca-II, investigated by fluorescence measurements, are reported. The receptor-substrate 1-Ca system is an example of multistability at the molecular level, triggered by a reversible modification of the receptor ability and evidenced by luminescence.
A new tetraoxa-tetraaza macrobicyclic anthracenyl luminescent receptor: control of the receptor-substrate stoichiometry / C. Di Pietro, G. Guglielmo, S. Campagna, M. Diotti, A. Manfredi, S. Quici. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 22:10(1998 Oct), pp. 1037-1039.
A new tetraoxa-tetraaza macrobicyclic anthracenyl luminescent receptor: control of the receptor-substrate stoichiometry
A. ManfrediPenultimo
;
1998
Abstract
The luminescent receptor 1 incorporating anthracenyl groups as luminophores and a tetraoxa-tetraaza macrobicyclic receptor as the binding subunit has been synthesized and its interactions with Ca-II, investigated by fluorescence measurements, are reported. The receptor-substrate 1-Ca system is an example of multistability at the molecular level, triggered by a reversible modification of the receptor ability and evidenced by luminescence.
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