Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50-87%) epoxidation of alkenes under fluorous biphasic conditions.

Second-generation fluorous chiral (salen) manganese complexes / M Cavazzini, A. Manfredi, F. Montanari, S. Quici, G. Pozzi. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :21(2000), pp. 2171-2172.

Second-generation fluorous chiral (salen) manganese complexes

A. Manfredi
Secondo
;
2000

Abstract

Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50-87%) epoxidation of alkenes under fluorous biphasic conditions.
CATALYTIC ASYMMETRIC EPOXIDATION; SEPARATION; CHEMISTRY; PRODUCTS; REAGENTS; OLEFINS; MEDIA
Settore CHIM/06 - Chimica Organica
Settore CHIM/04 - Chimica Industriale
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/187371
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