A study on the ring opening of a number of epoxides 1 with trifluoroacetamide (2) under solid-liquid phase transfer catalysis (SL-PTC) conditions has been performed. The reaction is completely regioselective affording beta-amido alcohols 3 deriving from the attack of the nucleophile to the less substituted carbon atom of the oxirane ring. (C) 1997 Elsevier Science Ltd.
Regioselective opening of epoxides to beta-amido alcohols under solid-liquid PTC conditions / D. Albanese, D. Landini, M. Penso. - In: TETRAHEDRON. - ISSN 0040-4020. - 53:13(1997), pp. 4787-4790.
Regioselective opening of epoxides to beta-amido alcohols under solid-liquid PTC conditions
D. AlbanesePrimo
;D. LandiniSecondo
;
1997
Abstract
A study on the ring opening of a number of epoxides 1 with trifluoroacetamide (2) under solid-liquid phase transfer catalysis (SL-PTC) conditions has been performed. The reaction is completely regioselective affording beta-amido alcohols 3 deriving from the attack of the nucleophile to the less substituted carbon atom of the oxirane ring. (C) 1997 Elsevier Science Ltd.
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