Reactions of the binuclear platinum(II) trihydrido complex. [Pt-2{(Ph2P)(2)(CH2)(4)}(2)(H)(3)][BF4], with styrene or ethylene, at room temperature and low pressure, give mu-alkylidene, mu-hydrido cationic species [Pt-2{(Ph2P)(2)(CH2)(4)}(2)(mu-CHCH2R)(mu-H)][BF4] (R = C6H5, 1; H, 2) together with an unexpected phosphido-bridged binuclear platinum(II) compound (3), originating from cleavage of a P-C bond in the coordinated diphosphine. Complexes 1-3 are discussed on the basis of FAB MS, IR and multinuclear NMR spectra in solution. (C) 2000 Elsevier Science S.A. All rights reserved.

Binuclear hydride platinum(II) complexes: syntheses of [{Pt(P-P)}(2)(mu-CHCH2R)(mu-H)][BF4] (R = C6H5, H) and easy cleavage of a P-C bond in a chelating 1,4-bis (diphenyl)phosphinobutane (P-P) / A. Bandini, G. Banditelli, G. Minghetti. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 595:2(2000), pp. 224-231.

Binuclear hydride platinum(II) complexes: syntheses of [{Pt(P-P)}(2)(mu-CHCH2R)(mu-H)][BF4] (R = C6H5, H) and easy cleavage of a P-C bond in a chelating 1,4-bis (diphenyl)phosphinobutane (P-P)

A. Bandini
Primo
;
G. Banditelli
Secondo
;
2000

Abstract

Reactions of the binuclear platinum(II) trihydrido complex. [Pt-2{(Ph2P)(2)(CH2)(4)}(2)(H)(3)][BF4], with styrene or ethylene, at room temperature and low pressure, give mu-alkylidene, mu-hydrido cationic species [Pt-2{(Ph2P)(2)(CH2)(4)}(2)(mu-CHCH2R)(mu-H)][BF4] (R = C6H5, 1; H, 2) together with an unexpected phosphido-bridged binuclear platinum(II) compound (3), originating from cleavage of a P-C bond in the coordinated diphosphine. Complexes 1-3 are discussed on the basis of FAB MS, IR and multinuclear NMR spectra in solution. (C) 2000 Elsevier Science S.A. All rights reserved.
Settore CHIM/03 - Chimica Generale e Inorganica
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/186999
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 23
  • ???jsp.display-item.citation.isi??? 21
social impact