The rate of halogen metathesis between halogenoalkanes RX 1-4 (X = F, Cl, Br, I) and aqueous concentrated hydrogen halides HY (Y = Cl, Br, I) is strongly accelerated under phase-transfer catalysis conditions, without solvent. The amount and nature of the nucleophilic species in the organic phase were determined.
FINKELSTEIN REACTION WITH AQUEOUS HYDROGEN HALIDES EFFICIENTLY CATALYZED BY LIPOPHILIC QUARTERNARY ONIUM SALTS / D. LANDINI, D. ALBANESE, S. MOTTADELLI, M. PENSO. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :18(1992), pp. 2309-2311.
Titolo: | FINKELSTEIN REACTION WITH AQUEOUS HYDROGEN HALIDES EFFICIENTLY CATALYZED BY LIPOPHILIC QUARTERNARY ONIUM SALTS |
Autori: | LANDINI, DARIO (Primo) ALBANESE, DOMENICO (Secondo) |
Settore Scientifico Disciplinare: | Settore CHIM/04 - Chimica Industriale |
Data di pubblicazione: | 1992 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/p19920002309 |
Appare nelle tipologie: | 01 - Articolo su periodico |
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