Enantiomerically pure P-tolyl sulphinyl-N,N-dimethylthioacetamide (1) was prepared starting from (-)-(S)-menthyl toluene-p-sulphinate. Aldol-type condensation of (1) and subsequent removal of the Sulphinyl group open an entry to optically active β-hydroxy thioacetamides in 40-90% e.e.

ASYMMETRIC-SYNTHESIS OF BETA-HYDROXYTHIOACETAMIDES MEDIATED BY ENANTIOMERICALLY PURE SULFINYL DERIVATIVES / M. CINQUINI, A. MANFREDI, H. MOLINARI, A. RESTELLI. - In: TETRAHEDRON. - ISSN 0040-4020. - 41:21(1985), pp. 4929-4936.

ASYMMETRIC-SYNTHESIS OF BETA-HYDROXYTHIOACETAMIDES MEDIATED BY ENANTIOMERICALLY PURE SULFINYL DERIVATIVES

A. MANFREDI;
1985

Abstract

Enantiomerically pure P-tolyl sulphinyl-N,N-dimethylthioacetamide (1) was prepared starting from (-)-(S)-menthyl toluene-p-sulphinate. Aldol-type condensation of (1) and subsequent removal of the Sulphinyl group open an entry to optically active β-hydroxy thioacetamides in 40-90% e.e.
Settore CHIM/06 - Chimica Organica
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/185737
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 15
  • ???jsp.display-item.citation.isi??? 13
social impact