The title compound Rh6(CO)10(DPM)3 (DPM bis(diphenylphosphino)-methane), obtained by heating Rh6(CO)16 and DPM in toluene, contains an octahedral rhodium cluster, with a mean RhRh bond length of 2.783 Å, which bears four triple bridging and six terminal carbonyl ligands, and three DPM molecules chelating pairs of adjacent metal atoms (mean RhP 2.307 Å). Thus each Rh atom is connected to one phosphorous atom and to one terminal and two triple-bridging carbonyl ligands. © 1982.
Synthesis and structural characterization of tetra-μ3-carbonylhexacarbonyltris[bis(diphenylphosphino)methane]-hexarhodium / A. Ceriotti, G. Ciani, L. Garlaschelli, U. Sartorelli, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 229:1(1982), pp. C9-C9-C12.
Synthesis and structural characterization of tetra-μ3-carbonylhexacarbonyltris[bis(diphenylphosphino)methane]-hexarhodium
A. CeriottiPrimo
;G. CianiSecondo
;L. Garlaschelli;A. SironiUltimo
1982
Abstract
The title compound Rh6(CO)10(DPM)3 (DPM bis(diphenylphosphino)-methane), obtained by heating Rh6(CO)16 and DPM in toluene, contains an octahedral rhodium cluster, with a mean RhRh bond length of 2.783 Å, which bears four triple bridging and six terminal carbonyl ligands, and three DPM molecules chelating pairs of adjacent metal atoms (mean RhP 2.307 Å). Thus each Rh atom is connected to one phosphorous atom and to one terminal and two triple-bridging carbonyl ligands. © 1982.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
