The title compound Rh6(CO)10(DPM)3 (DPM bis(diphenylphosphino)-methane), obtained by heating Rh6(CO)16 and DPM in toluene, contains an octahedral rhodium cluster, with a mean RhRh bond length of 2.783 Å, which bears four triple bridging and six terminal carbonyl ligands, and three DPM molecules chelating pairs of adjacent metal atoms (mean RhP 2.307 Å). Thus each Rh atom is connected to one phosphorous atom and to one terminal and two triple-bridging carbonyl ligands. © 1982.

Synthesis and structural characterization of tetra-μ3-carbonylhexacarbonyltris[bis(diphenylphosphino)methane]-hexarhodium / A. Ceriotti, G. Ciani, L. Garlaschelli, U. Sartorelli, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 229:1(1982), pp. C9-C9-C12.

Synthesis and structural characterization of tetra-μ3-carbonylhexacarbonyltris[bis(diphenylphosphino)methane]-hexarhodium

A. Ceriotti
Primo
;
G. Ciani
Secondo
;
L. Garlaschelli;A. Sironi
Ultimo
1982

Abstract

The title compound Rh6(CO)10(DPM)3 (DPM bis(diphenylphosphino)-methane), obtained by heating Rh6(CO)16 and DPM in toluene, contains an octahedral rhodium cluster, with a mean RhRh bond length of 2.783 Å, which bears four triple bridging and six terminal carbonyl ligands, and three DPM molecules chelating pairs of adjacent metal atoms (mean RhP 2.307 Å). Thus each Rh atom is connected to one phosphorous atom and to one terminal and two triple-bridging carbonyl ligands. © 1982.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/185606
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