The novel anion [Rh17(CO)30]3-, which has been obtained by refluxing a mixture of Rh4(CO)12 and NaOH (OH- : Rh, 1 : 5.5) in propan-2-ol, has been shown by X-ray crystallography to contain a cluster which is a fragment of a hexagonal close-packed structure (3 layers: 6/7/4) and is derived from the twinned cuboctahedron present in the anions [Rh13H5-n(CO) 24]n-, with the other four rhodium atoms capping square faces.
Synthesis and x-ray characterization of the high-nuclearity [Rh 17(μ3-CO)3-(μ-CO)15(CO) 12]3- anion containing a tetracapped twinned cuboctahedral cluster / G. Ciani, A. Magni, A. Sironi, S. Martinengo. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :24(1981), pp. 1280-1282.
Titolo: | Synthesis and x-ray characterization of the high-nuclearity [Rh 17(μ3-CO)3-(μ-CO)15(CO) 12]3- anion containing a tetracapped twinned cuboctahedral cluster | |
Autori: | CIANI, GIANFRANCO MARIA (Primo) SIRONI, ANGELO AGOSTINO DANIELE (Penultimo) | |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica | |
Data di pubblicazione: | 1981 | |
Rivista: | ||
Tipologia: | Article (author) | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/C39810001280 | |
Appare nelle tipologie: | 01 - Articolo su periodico |