The anion [Rh10S(CO)22]2-, obtained by slow decomposition of [Rh6(CO)14(SCN)2] 2- in tetrahydrofuran, has been investigated by X-ray diffraction; it contains a bicapped square-antiprismatic metal atom cluster, with an interstitial sulphur atom.
Synthesis and x-ray characterization of the novel [Rh10S(CO) 10(μ-CO)12]2- anion; a bicapped square-antiprismatic cluster containing an interstitial sulphur atom / G. Ciani, L. Garlaschelli, A. Sironi, S. Martinengo. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 11(1981), pp. 563-565. [10.1039/C3981000563b]
Synthesis and x-ray characterization of the novel [Rh10S(CO) 10(μ-CO)12]2- anion; a bicapped square-antiprismatic cluster containing an interstitial sulphur atom
G. CianiPrimo
;L. GarlaschelliSecondo
;A. SironiPenultimo
;
1981
Abstract
The anion [Rh10S(CO)22]2-, obtained by slow decomposition of [Rh6(CO)14(SCN)2] 2- in tetrahydrofuran, has been investigated by X-ray diffraction; it contains a bicapped square-antiprismatic metal atom cluster, with an interstitial sulphur atom.
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