Several sulfides and bicyclo[3.2.0]hept-2-en-6-one were enantioselectively oxidized to the corresponding sulfoxides and oxa lactones by a crude preparation of the two diketocamphane monooxygenases from Pseudomonas putida. The reactions were carried out in a membrane reactor with the use of poly(ethylene glycol)-N6-(2-aminoethyl)-NAD and coenzyme regeneration by the formate/formate dehydrogenase system.
Enantioselective oxidations catalyzed by diketocamphane monooxygenase from Pseudomonas putida with macromolecular NAD in a membrane reactor / P. Pasta, G. Carrea, N. Gaggero, G. Grogan, A. Willetts,. - In: BIOTECHNOLOGY LETTERS. - ISSN 0141-5492. - 18:10(1996), pp. 1123-1128. [10.1007/BF00128578]
Enantioselective oxidations catalyzed by diketocamphane monooxygenase from Pseudomonas putida with macromolecular NAD in a membrane reactor
N. Gaggero;
1996
Abstract
Several sulfides and bicyclo[3.2.0]hept-2-en-6-one were enantioselectively oxidized to the corresponding sulfoxides and oxa lactones by a crude preparation of the two diketocamphane monooxygenases from Pseudomonas putida. The reactions were carried out in a membrane reactor with the use of poly(ethylene glycol)-N6-(2-aminoethyl)-NAD and coenzyme regeneration by the formate/formate dehydrogenase system.
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