Protic and Lewis acids cause partial backbone rearrangement involving the C-D ring junction in the normal steroid series with ring contraction and formation of 12,14α-cyclo-12,13-seco-5α-cholest-13(17)-ene compounds. 12-Methylene rather than 13-methyl rearrangement is suggested and a revision of a previously proposed structure is given.

Acid-catalysed backbone rearrangement involving the C-D ring junction in normal steroid series / M. Anastasia, A.M. Soave, A. Scala. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :10(1978), pp. 1131-1132. [10.1039/P19780001131]

Acid-catalysed backbone rearrangement involving the C-D ring junction in normal steroid series

M. Anastasia
Primo
;
1978

Abstract

Protic and Lewis acids cause partial backbone rearrangement involving the C-D ring junction in the normal steroid series with ring contraction and formation of 12,14α-cyclo-12,13-seco-5α-cholest-13(17)-ene compounds. 12-Methylene rather than 13-methyl rearrangement is suggested and a revision of a previously proposed structure is given.
Settore BIO/10 - Biochimica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/185425
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