Chloroperoxidase catalysed epoxidation of styrene derivatives by t-BuOOH preferentially gives (R) oxides with ee values between 28 and 68%. The data support the view of oxygen delivery from the ferryl oxygen directly to the substrate.

Enantioselective epoxidation of styrene derivatives by chloroperoxidase catalysis / S. Colonna, N. Gaggero, L. Casella, G. Carrea, P. Pasta. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 4:6(1993), pp. 1325-1330. [10.1016/S0957-4166(00)80243-8]

Enantioselective epoxidation of styrene derivatives by chloroperoxidase catalysis

S. Colonna;N. Gaggero;
1993

Abstract

Chloroperoxidase catalysed epoxidation of styrene derivatives by t-BuOOH preferentially gives (R) oxides with ee values between 28 and 68%. The data support the view of oxygen delivery from the ferryl oxygen directly to the substrate.
chloroperoxidase; epoxide; styrene oxide; catalysis; enzyme; stereochemistry
Settore CHIM/06 - Chimica Organica
TETRAHEDRON-ASYMMETRY
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/185393
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