A stereoselective synthesis of crinosterol, (22E,24S)-ergosta-5,22-dien- 3β-ol, was developed from (20S)-6β-acetoxy-3α,5-cyclo-5α- pregnane-20-carbaldehyde using the Claisen rearrangement of an appropriate precursor of established absolute configuration.

Stereoselective synthesis of crinosterol [(22E,24S)-ergosta-5,22-dien- 3β-ol] / M. Anastasia, P. Allevi, P. Ciuffreda, A. Fiecchi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - (1983), pp. 2365-2367.

Stereoselective synthesis of crinosterol [(22E,24S)-ergosta-5,22-dien- 3β-ol]

M. Anastasia
Primo
;
P. Allevi
Secondo
;
P. Ciuffreda
Penultimo
;
1983

Abstract

A stereoselective synthesis of crinosterol, (22E,24S)-ergosta-5,22-dien- 3β-ol, was developed from (20S)-6β-acetoxy-3α,5-cyclo-5α- pregnane-20-carbaldehyde using the Claisen rearrangement of an appropriate precursor of established absolute configuration.
Settore BIO/10 - Biochimica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/185267
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