The aldol-type condensation of enantiomerically pure α-sulphinylacetamides is described. The stereochemical outcome of the reaction mainly depends on the nature of the base used to generate the enolate. Experimental evidences allow the identification of preferred reaction paths.
Asymmetric synthesis of beta-hydroxyacetamides mediated by enantiomerically pure sulphinyl derivatives / R. Annunziata, M. Cinquini, F. Cozzi, F. Montanari, A. Restelli. - In: TETRAHEDRON. - ISSN 0040-4020. - 40:19(1984), pp. 3815-3822. [10.1016/S0040-420(01)85812-8]
Asymmetric synthesis of beta-hydroxyacetamides mediated by enantiomerically pure sulphinyl derivatives
R. Annunziata;M. Cinquini;F. Cozzi;
1984
Abstract
The aldol-type condensation of enantiomerically pure α-sulphinylacetamides is described. The stereochemical outcome of the reaction mainly depends on the nature of the base used to generate the enolate. Experimental evidences allow the identification of preferred reaction paths.
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