Asymmetrie synthesis (up to 99%) of β-hydroxy-N,N-dimethylacetamides was achieved starting from aldehydes and an optically active sulphoxide containing synthon, the sense of chiral discrimination depending on the intermediate metal enolate.
Enantiomerically pure alpha-sulphinyl N,N-dimethylacetamide: a new efficient reagent for enantioselective aldol type condensation / R. Annunziata, M. Cinquini, F. Cozzi, F. Montanari, A. Restelli. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :20(1983), pp. 1138-1139.
Enantiomerically pure alpha-sulphinyl N,N-dimethylacetamide: a new efficient reagent for enantioselective aldol type condensation
R. Annunziata;M. Cinquini;F. Cozzi;
1983
Abstract
Asymmetrie synthesis (up to 99%) of β-hydroxy-N,N-dimethylacetamides was achieved starting from aldehydes and an optically active sulphoxide containing synthon, the sense of chiral discrimination depending on the intermediate metal enolate.
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