The anion [Rh5(CO)14I]2- (1) has been obtained by reaction of I- with Rh4(CO)12; the cluster, containing five metal atoms, consists of an elongated trigonal bipyramid with the iodide ligand terminally bound to an apical rhodium atom.

Synthesis and X-ray crystal structure of the [Rh5(CO) 8(μ-CO)6I]2- anion containing a trigonal bipyramidal rhodium cluster / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :23(1979), pp. 1059-1061.

Synthesis and X-ray crystal structure of the [Rh5(CO) 8(μ-CO)6I]2- anion containing a trigonal bipyramidal rhodium cluster

G. Ciani
Secondo
;
A. Sironi
Ultimo
1979

Abstract

The anion [Rh5(CO)14I]2- (1) has been obtained by reaction of I- with Rh4(CO)12; the cluster, containing five metal atoms, consists of an elongated trigonal bipyramid with the iodide ligand terminally bound to an apical rhodium atom.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/184893
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