The anion [Co6(CO)16P]- has been obtained by reaction of PCl3 with Na[Co(CO)4]; the six metal atoms form four triangles linked in a chain surrounding a 'semi-interstitial' phosphide atom.
Synthesis and X-ray crystal structure of the anion [Co6(CO) 14(μ-CO)2P]-; an example of a 'semi-interstitial phosphide' / P. Chini, G. Ciani, S. Martinengo, A. Sironi, L. Longhetti, B. T. Heaton. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :4(1979), pp. 188-189.
Synthesis and X-ray crystal structure of the anion [Co6(CO) 14(μ-CO)2P]-; an example of a 'semi-interstitial phosphide'
G. CianiSecondo
;A. Sironi;
1979
Abstract
The anion [Co6(CO)16P]- has been obtained by reaction of PCl3 with Na[Co(CO)4]; the six metal atoms form four triangles linked in a chain surrounding a 'semi-interstitial' phosphide atom.
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