The stereochemistries of cycloadditions of mesitonitrile oxide to norbornadiene and nine 7-substituted derivatives have been investigated. The stereoselectivities are controlled primarily by torsional effects which are altered by 7-substituents.
STEREOSELECTIVITIES OF MESITONITRILE OXIDE CYCLO-ADDITIONS TO 7-SUBSTITUTED NORBORNADIENES / L. Dal Bo, M. De Amici, C. De Micheli, R. Gandolfi, K. N. Houk. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 30:7(1989), pp. 807-810.
STEREOSELECTIVITIES OF MESITONITRILE OXIDE CYCLO-ADDITIONS TO 7-SUBSTITUTED NORBORNADIENES
M. De Amici;C. De Micheli;
1989
Abstract
The stereochemistries of cycloadditions of mesitonitrile oxide to norbornadiene and nine 7-substituted derivatives have been investigated. The stereoselectivities are controlled primarily by torsional effects which are altered by 7-substituents.
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