Lipase catalysed resolution of (R)- and (S)-1-trimethylsilyl-1-alkyn-3-ols: Useful intermediates for the synthesis of optically active gamma-lactones

Allevi, P.; Ciuffreda, P.; Anastasia, M.

doi:10.1016/S0957-4166(96)00475-2

Various (R)- and (S)-1-trimethylsilyl-1-alkyn-3-ols, chiral building units useful for the synthesis of biologically active compounds, have been efficiently resolved by enantioselective acetylation mediated by immobilized lipase PS. The resolution is applied to the synthesis of (R)- and (S)-5-octyl-2-(5H)-furanones

Lipase catalysed resolution of (R)- and (S)-1-trimethylsilyl-1-alkyn-3-ols: Useful intermediates for the synthesis of optically active gamma-lactones / P. Allevi, P. Ciuffreda, M. Anastasia. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 8:1(1997), pp. 93-99. [10.1016/S0957-4166(96)00475-2]

Titolo:	Lipase catalysed resolution of (R)- and (S)-1-trimethylsilyl-1-alkyn-3-ols: Useful intermediates for the synthesis of optically active gamma-lactones
Autori:	ALLEVI, PIETRO (Primo) CIUFFREDA, PIERANGELA (Secondo) ANASTASIA, MARIO (Ultimo)
Parole Chiave:	CHIRAL BUILDING BLOCKS ; ENANTIOSELECTIVE ACETYLATION ; ENZYMATIC ACETYLATION ; FURANONES
Settore Scientifico Disciplinare:	Settore BIO/10 - Biochimica
Data di pubblicazione:	1997
Rivista:	TETRAHEDRON-ASYMMETRY
Tipologia:	Article (author)
Digital Object Identifier (DOI):	http://dx.doi.org/10.1016/S0957-4166(96)00475-2
Appare nelle tipologie:	01 - Articolo su periodico

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