The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel irregular dodecanuclear metallic skeleton which shows a trigonal-prismatic and a distorted square-antiprismatic hole occupied by two encapsulated nitrogen atoms.
Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :23(1986), pp. 1742-1744.
Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms
G. CianiSecondo
;A. SironiUltimo
1986
Abstract
The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel irregular dodecanuclear metallic skeleton which shows a trigonal-prismatic and a distorted square-antiprismatic hole occupied by two encapsulated nitrogen atoms.
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