The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel irregular dodecanuclear metallic skeleton which shows a trigonal-prismatic and a distorted square-antiprismatic hole occupied by two encapsulated nitrogen atoms.

Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :23(1986), pp. 1742-1744.

Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms

G. Ciani
Secondo
;
A. Sironi
Ultimo
1986

Abstract

The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel irregular dodecanuclear metallic skeleton which shows a trigonal-prismatic and a distorted square-antiprismatic hole occupied by two encapsulated nitrogen atoms.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/184204
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