The stereoselective introduction of an allylic alcohol function into chiral aldehydes is readily achieved by sequential condensation of aldehydes with an allylic sulphinyl anion and thiophile-promoted desulphurization of the resulting α-substituted allylic sulphoxides.

CRAM-SELECTIVE ADDITION OF ALPHA-ALLYL SULFINYL ANION TO CHIRAL ALDEHYDES - SYNTHESIS OF (E)-1,4-DIHYDROXYALK-2-ENES / R. ANNUNZIATA, M. CINQUINI, F. COZZI, L. RAIMONDI. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :4(1986), pp. 366-367.

CRAM-SELECTIVE ADDITION OF ALPHA-ALLYL SULFINYL ANION TO CHIRAL ALDEHYDES - SYNTHESIS OF (E)-1,4-DIHYDROXYALK-2-ENES

R. ANNUNZIATA
Primo
;
M. CINQUINI
Secondo
;
F. COZZI
Penultimo
;
L. RAIMONDI
Ultimo
1986

Abstract

The stereoselective introduction of an allylic alcohol function into chiral aldehydes is readily achieved by sequential condensation of aldehydes with an allylic sulphinyl anion and thiophile-promoted desulphurization of the resulting α-substituted allylic sulphoxides.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/184183
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