Reaction of ethyl chloroformate with 3-(2-aryl-1-hydroxyethylidene)indol-2(3H)-ones 3 affords the corresponding ethyl 3-[(2-aryl-1-ethoxycarbonyloxy)ethenyl]-2-(ethoxycarbonyloxy)indole-1-carboxylates 4 from which ethyl 6-(ethoxycarbonyloxy)-11H-benzo[a]carbazole-11-carboxylates 5a,b, the corresponding 3H,10H-pyrrolo[3,2-1]-5c, 10H-thieno[3,2-a]- 5d and 10H-thieno[2,3-a]carbazole-10-carboxylate 5e are obtained via 6-pi-electrocyclization.

Synthesis of [a]annulated carbazoles from indol-2(3H)-one / E.M. Beccalli, A. Marchesini, T. Pilati. - In: SYNTHESIS. - ISSN 0039-7881. - :9(1992), pp. 891-894.

Synthesis of [a]annulated carbazoles from indol-2(3H)-one

E.M. Beccalli
Primo
;
A. Marchesini
Secondo
;
1992

Abstract

Reaction of ethyl chloroformate with 3-(2-aryl-1-hydroxyethylidene)indol-2(3H)-ones 3 affords the corresponding ethyl 3-[(2-aryl-1-ethoxycarbonyloxy)ethenyl]-2-(ethoxycarbonyloxy)indole-1-carboxylates 4 from which ethyl 6-(ethoxycarbonyloxy)-11H-benzo[a]carbazole-11-carboxylates 5a,b, the corresponding 3H,10H-pyrrolo[3,2-1]-5c, 10H-thieno[3,2-a]- 5d and 10H-thieno[2,3-a]carbazole-10-carboxylate 5e are obtained via 6-pi-electrocyclization.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/184147
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