The neutral species [Rh12H2(CO)25], obtained by reaction of [Rh14(CO)25]4- with CF3CO2H in the presence of CO and chloride ions, contains a new Rh12 metallic array formed by superimposition of three face-sharing octahedral units, and in donor solvents readily gives the [Rh12H(CO)25]- monoanion.
Synthesis and x-ray crystal structure of the cluster compound [Rh12H2(μ3-CO)3(μ-CO) 9(CO)13] containing a metallic array formed by three superimposed cofacial octahedral units / G. Ciani, A. Sironi, S. Martinengo. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :24(1985), pp. 1757-1759.
Synthesis and x-ray crystal structure of the cluster compound [Rh12H2(μ3-CO)3(μ-CO) 9(CO)13] containing a metallic array formed by three superimposed cofacial octahedral units
G. Ciani;A. Sironi;
1985
Abstract
The neutral species [Rh12H2(CO)25], obtained by reaction of [Rh14(CO)25]4- with CF3CO2H in the presence of CO and chloride ions, contains a new Rh12 metallic array formed by superimposition of three face-sharing octahedral units, and in donor solvents readily gives the [Rh12H(CO)25]- monoanion.
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