The anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), obtained by condensation of [Rh6N(CO)15]- and [M(CO)4]-, contain a metallic array consisting of a trigonal prism capped on a square face, with the nitride inside the prismatic hole; the mixed-metal species show an unexpected migration of the entering metal from the capping position to the vertices of the prism.
A new family of nitrido carbonyl clusters. Synthesis and structural characterization of the anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), and evidence for metal atom migration in the cluster / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 23(1984), pp. 1577-1578.
A new family of nitrido carbonyl clusters. Synthesis and structural characterization of the anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), and evidence for metal atom migration in the cluster
G. CianiSecondo
;A. SironiUltimo
1984
Abstract
The anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), obtained by condensation of [Rh6N(CO)15]- and [M(CO)4]-, contain a metallic array consisting of a trigonal prism capped on a square face, with the nitride inside the prismatic hole; the mixed-metal species show an unexpected migration of the entering metal from the capping position to the vertices of the prism.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
