The anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), obtained by condensation of [Rh6N(CO)15]- and [M(CO)4]-, contain a metallic array consisting of a trigonal prism capped on a square face, with the nitride inside the prismatic hole; the mixed-metal species show an unexpected migration of the entering metal from the capping position to the vertices of the prism.

A new family of nitrido carbonyl clusters. Synthesis and structural characterization of the anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), and evidence for metal atom migration in the cluster / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 23(1984), pp. 1577-1578.

A new family of nitrido carbonyl clusters. Synthesis and structural characterization of the anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), and evidence for metal atom migration in the cluster

G. Ciani
Secondo
;
A. Sironi
Ultimo
1984

Abstract

The anions [Rh6MN(CO)15]2- (M=Co, Rh, or Ir), obtained by condensation of [Rh6N(CO)15]- and [M(CO)4]-, contain a metallic array consisting of a trigonal prism capped on a square face, with the nitride inside the prismatic hole; the mixed-metal species show an unexpected migration of the entering metal from the capping position to the vertices of the prism.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/184028
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