Various gold(III) derivatives of pyrazoles, pzH, were obtained and characterized. Besides the salt [3,5-Ph2pzH2][AuCl4], they included adducts, AuCl3·pzH, μ-pyrazolato-N,N′-derivatives, [Cl2Au(pz)]n (such as: n = 2 and pz = 3,5-diphenyl-4-chloropyrazolato), and one derivative containing both a neutral pyrazole and a pyrazolato ligand, Cl2Au(3,5-Ph2pz-N)(3,5-Ph2pzH).
SOME GOLD(III) DERIVATIVES OF PYRAZOLES / A. BANDINI, G. BANDITELLI, F. BONATI, G. MINGHETTI, M. PINILLOS. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 99:2(1985), pp. 165-168.
SOME GOLD(III) DERIVATIVES OF PYRAZOLES
A. BANDINIPrimo
;G. BANDITELLISecondo
;
1985
Abstract
Various gold(III) derivatives of pyrazoles, pzH, were obtained and characterized. Besides the salt [3,5-Ph2pzH2][AuCl4], they included adducts, AuCl3·pzH, μ-pyrazolato-N,N′-derivatives, [Cl2Au(pz)]n (such as: n = 2 and pz = 3,5-diphenyl-4-chloropyrazolato), and one derivative containing both a neutral pyrazole and a pyrazolato ligand, Cl2Au(3,5-Ph2pz-N)(3,5-Ph2pzH).
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