Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os 5(CO)15]2- together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2 (1); X-ray analysis shows that (1) exhibits an unusual type of metal-carbonyl linkage.

The synthesis and x-ray structure analysis of Os6(CO) 17(NC5H5)2: A cluster compound with an unusual mode of metal-CO bonding / B. F. G. Johnson, J. Lewis, M. McPartlin, M. A. Pearsall, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :16(1984), pp. 1089-1090.

The synthesis and x-ray structure analysis of Os6(CO) 17(NC5H5)2: A cluster compound with an unusual mode of metal-CO bonding

A. Sironi
Ultimo
1984

Abstract

Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os 5(CO)15]2- together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2 (1); X-ray analysis shows that (1) exhibits an unusual type of metal-carbonyl linkage.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/183969
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