Pyrolysis of Os3(CO)12 with elemental sulphur gives a range of clusters including Os3(S)2(CO)9, Os5S(CO)15, Os6(CO)18, Os 7(S)2(CO)20, and Os10(S) 2(CO)23 (1); X-ray analysis shows that (1) has a new type of Os10 metal core geometry.

A new type of decaosmium cluster geometry : The synthesis and x-ray structure analysis of Os10(S)2(CO)23 / J.P. Attard, B.F.G. Johnson, J. Lewis, J.M. Mace, M. Mcpartlin, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :9(1984), pp. 595-597. [10.1039/C39840000595]

A new type of decaosmium cluster geometry : The synthesis and x-ray structure analysis of Os10(S)2(CO)23

A. Sironi
1984

Abstract

Pyrolysis of Os3(CO)12 with elemental sulphur gives a range of clusters including Os3(S)2(CO)9, Os5S(CO)15, Os6(CO)18, Os 7(S)2(CO)20, and Os10(S) 2(CO)23 (1); X-ray analysis shows that (1) has a new type of Os10 metal core geometry.
Settore CHIM/03 - Chimica Generale e Inorganica
JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/183932
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