The anion [Rh11(CO)23]3-, obtained through oxidation of [Rh7(CO)16]3- or various redox condensations, contains a metal polyhedron of ideal D3h, symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.

A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3- trianion / A. Fumagalli, S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :8(1983), pp. 453-455.

A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3- trianion

G. Ciani
Penultimo
;
A. Sironi
Ultimo
1983

Abstract

The anion [Rh11(CO)23]3-, obtained through oxidation of [Rh7(CO)16]3- or various redox condensations, contains a metal polyhedron of ideal D3h, symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/183820
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