The anion [Rh11(CO)23]3-, obtained through oxidation of [Rh7(CO)16]3- or various redox condensations, contains a metal polyhedron of ideal D3h, symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.
A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3- trianion / A. Fumagalli, S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 8(1983), pp. 453-455.
A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3- trianion
G. CianiPenultimo
;A. SironiUltimo
1983
Abstract
The anion [Rh11(CO)23]3-, obtained through oxidation of [Rh7(CO)16]3- or various redox condensations, contains a metal polyhedron of ideal D3h, symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.
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