A regio- and stereoselective didehydrodimerization procedure, whose key step involves the anodic oxidation, allows the conversion of beta-anilinoacrylic alkaloids belonging to the Aspidosperma class, typified by tabersonine (1) and its 3-oxo derivative 2, into the hitherto unknown 16,10'-didehydro dimers 3 and 7, respectively.

ASPIDOSPERMA ALKALOIDS - A NEW DIDEHYDRODIMERIZATION MODE OF BETA-ANILINOACRYLIC ALKALOIDS BY ANODIC-OXIDATION / G. PALMISANO, B. DANIELI, G. LESMA, M. SANTAGOSTINO, G. FIORI, L. TOMA. - In: HELVETICA CHIMICA ACTA. - ISSN 0018-019X. - 75:3(1992), pp. 813-824. [10.1002/hlca.19920750316]

ASPIDOSPERMA ALKALOIDS - A NEW DIDEHYDRODIMERIZATION MODE OF BETA-ANILINOACRYLIC ALKALOIDS BY ANODIC-OXIDATION

B. DANIELI
Secondo
;
G. LESMA;
1992

Abstract

A regio- and stereoselective didehydrodimerization procedure, whose key step involves the anodic oxidation, allows the conversion of beta-anilinoacrylic alkaloids belonging to the Aspidosperma class, typified by tabersonine (1) and its 3-oxo derivative 2, into the hitherto unknown 16,10'-didehydro dimers 3 and 7, respectively.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/183693
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