Beckmann rearrangement of Δ4-6-hydroxyimino steroids gave solely the products of vinyl migration. Compounds having a 3-hydroxy or 3-acetoxy group suffer elimination of the substituent during the reaction.
Beckmann rearrangement of delta-4-6-hydroxyimino steroids / M. Anastasia, P. Allevi, P. Ciuffreda, A. Fiecchi, A. Scala. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :12(1986), pp. 2123-2126.
Beckmann rearrangement of delta-4-6-hydroxyimino steroids
M. ANASTASIA;P. ALLEVI;P. CIUFFREDA;
1986
Abstract
Beckmann rearrangement of Δ4-6-hydroxyimino steroids gave solely the products of vinyl migration. Compounds having a 3-hydroxy or 3-acetoxy group suffer elimination of the substituent during the reaction.
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