The reactions of ArNSO (Ar = p-MeC6H4) with cis-Mo(O)2(chel)2 (chel = S2CNEt2, CH3COCH- COCHH3) give the molybdenum(VI) oxo-arylimido derivatives, Mo(O)(NAr)(hel)2, and sulphur dioxide. From cis-Mo(O)2(S2CNEt2)2 and CyNCO (Cy = C6H11) the dimeric Mo2O3(S2CNEt2)4 is obtained, with the concomitant formation of carbon dioxide and biuret, (CyNHCO)2NCy. The spectroscopic properties of the molybdenum(VI) oxo-arylimido derivatives are reported and the possible reaction mechanisms are discussed.

The reaction of molibdenum(VI) dioxo derivatives with hetrocumulenes / S. Cenini, M. Pizzotti. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 42:C(1980), pp. 65-68.

The reaction of molibdenum(VI) dioxo derivatives with hetrocumulenes

S. Cenini;M. Pizzotti
1980

Abstract

The reactions of ArNSO (Ar = p-MeC6H4) with cis-Mo(O)2(chel)2 (chel = S2CNEt2, CH3COCH- COCHH3) give the molybdenum(VI) oxo-arylimido derivatives, Mo(O)(NAr)(hel)2, and sulphur dioxide. From cis-Mo(O)2(S2CNEt2)2 and CyNCO (Cy = C6H11) the dimeric Mo2O3(S2CNEt2)4 is obtained, with the concomitant formation of carbon dioxide and biuret, (CyNHCO)2NCy. The spectroscopic properties of the molybdenum(VI) oxo-arylimido derivatives are reported and the possible reaction mechanisms are discussed.
Settore CHIM/03 - Chimica Generale e Inorganica
INORGANICA CHIMICA ACTA
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/182812
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