The Pseudomonas fluorescens lipase-catalyzed transesterification of 2-methyl alkanols 1 and the 2-substituted oxiranemethanols 2 with vinyl acetate in organic solvents has been studied and the results discussed in terms of steric and electronic demand within the recently postulated models of the lipase active site.
An insight into the active site of Pseudomonas fluorescens (P. cepacia) lipase to define the stereochemical demand for the transesterification in organic solvents / P. Ferraboschi, S. Casati, S. De Grandi, P. Grisenti, E. Santaniello. - In: BIOCATALYSIS. - ISSN 0886-4454. - 10:1-4(1994), pp. 279-288. [10.3109/10242429409065237]
An insight into the active site of Pseudomonas fluorescens (P. cepacia) lipase to define the stereochemical demand for the transesterification in organic solvents
P. FerraboschiPrimo
;S. CasatiSecondo
;E. SantanielloUltimo
1994
Abstract
The Pseudomonas fluorescens lipase-catalyzed transesterification of 2-methyl alkanols 1 and the 2-substituted oxiranemethanols 2 with vinyl acetate in organic solvents has been studied and the results discussed in terms of steric and electronic demand within the recently postulated models of the lipase active site.
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