Both vinyl and β-halogenoethyl sulphilimines can be obtained in optically active form via kinetic resolution in the elimination reaction of the latter promoted by chiral bases, with enantiomeric excesses of up to 73%; the influence of the resolving agent and of the leaving group on the chiral discrimination has also been examined.
Synthesis of optically active sulphilimines via chiral discrimination / R. Annunziata, M. Cinquini, S. Colonna, F. Cozzi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :0(1981), pp. 3118-3119.
Synthesis of optically active sulphilimines via chiral discrimination
R. AnnunziataPrimo
;M. CinquiniSecondo
;S. ColonnaPenultimo
;F. CozziUltimo
1981
Abstract
Both vinyl and β-halogenoethyl sulphilimines can be obtained in optically active form via kinetic resolution in the elimination reaction of the latter promoted by chiral bases, with enantiomeric excesses of up to 73%; the influence of the resolving agent and of the leaving group on the chiral discrimination has also been examined.File in questo prodotto:
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