By 2H n.m.r. spectroscopy it is shown that, during the conversion of cis-aconitic acid (1) into itaconic acid (2), the proton coming from the medium is introduced at C-2 of (1) on the 2-re,3-si face.
Stereochemistry of the introduction of the hydrogen atom at C-2 of cis-aconitic acid during its transformation into itaconic acid in aspergillus terreus: A 2H N.M.R. approach / B.M. Ranzi, F. Ronchetti, G. Russo, L. Toma. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :20(1981), pp. 1050-1051.
Stereochemistry of the introduction of the hydrogen atom at C-2 of cis-aconitic acid during its transformation into itaconic acid in aspergillus terreus: A 2H N.M.R. approach
F. RonchettiSecondo
;G. RussoPenultimo
;
1981
Abstract
By 2H n.m.r. spectroscopy it is shown that, during the conversion of cis-aconitic acid (1) into itaconic acid (2), the proton coming from the medium is introduced at C-2 of (1) on the 2-re,3-si face.
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