Optically active β-oxosulphoximides have been prepared by reaction of optically active α-metallated NS-dimethyl-S-phenylsulphoximide with carboxylic esters. Their reduction by sodium borohydride is stereoselective, the extent of asymmetric synthesis (up to 50%) depending on steric factors.

Asymmetric induction in the reduction of beta-oxosulphoximides by sodium borohydride / R. Annunziata, M. Cinquini, F. Cozzi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :0(1981), pp. 1109-1111.

Asymmetric induction in the reduction of beta-oxosulphoximides by sodium borohydride

R. Annunziata
Primo
;
M. Cinquini
Secondo
;
F. Cozzi
Ultimo
1981

Abstract

Optically active β-oxosulphoximides have been prepared by reaction of optically active α-metallated NS-dimethyl-S-phenylsulphoximide with carboxylic esters. Their reduction by sodium borohydride is stereoselective, the extent of asymmetric synthesis (up to 50%) depending on steric factors.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/182328
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