The reaction of (Ph3P)2Ru(CO)3 with (p-RC6H4N2)+(BF4-) (R = NO2, F, OMe, H) or (p-Me2NC6H4N2)+(BPh4-) gave arylazo complexes, [p-RC6H4N2Ru(CO)2(PPh3)2]+X-, which were protonated with HBF4 to give diimines [p-RC6H4N:NHRu(CO)2(PPh3)2]2+ (BF4-)2.
Arylazo and aryldiimine derivatives of ruthenium / S. Cenini, F. Porta, M. Pizzotti. - In: INORGANIC AND NUCLEAR CHEMISTRY LETTERS. - ISSN 0020-1650. - 10:11(1974), pp. 983-986.
Arylazo and aryldiimine derivatives of ruthenium
S. Cenini;F. Porta;M. Pizzotti
1974
Abstract
The reaction of (Ph3P)2Ru(CO)3 with (p-RC6H4N2)+(BF4-) (R = NO2, F, OMe, H) or (p-Me2NC6H4N2)+(BPh4-) gave arylazo complexes, [p-RC6H4N2Ru(CO)2(PPh3)2]+X-, which were protonated with HBF4 to give diimines [p-RC6H4N:NHRu(CO)2(PPh3)2]2+ (BF4-)2.
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