The C-26 atom of tomatidine, bearing the nitrogen atom, derives from the C-2 atom of MVA; from this it is inferred that the introduction of hydrogen at the C-25 atom of the Δ24 biosynthetic intermediate occurs from the 24-si, 25-si face.
Stereochemistry of the hydrogen introduction at C-25 in the biosynthesis of tomatidine / F. Ronchetti, G. Russo. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :19(1974), pp. 785-786.
Stereochemistry of the hydrogen introduction at C-25 in the biosynthesis of tomatidine
F. RonchettiPrimo
;G. RussoUltimo
1974
Abstract
The C-26 atom of tomatidine, bearing the nitrogen atom, derives from the C-2 atom of MVA; from this it is inferred that the introduction of hydrogen at the C-25 atom of the Δ24 biosynthetic intermediate occurs from the 24-si, 25-si face.
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