The product of the acid catalyzed rearrangement of 2-(1-naphthyl)-2,4,4-trimethyl-2,4-disilapentane is 2-(2-naphthyl)-2,4,4-trimethyl-2,4-disilapentane. This result completes the revision of a previous report in which 1,8-bis(trimethylsilyl)naphthalene was claimed to undergo acid catalyzed rearrangement to the 1,7-isomer.
The acid catalyzed isomerization of 2-(1-naphthyl)-2,4,4-trimethyl-s,4-disilapentane / U. Sjostrand, F. Cozzi, K. Mislow. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 179:3(1979), pp. 323-329.
The acid catalyzed isomerization of 2-(1-naphthyl)-2,4,4-trimethyl-s,4-disilapentane
F. CozziSecondo
;
1979
Abstract
The product of the acid catalyzed rearrangement of 2-(1-naphthyl)-2,4,4-trimethyl-2,4-disilapentane is 2-(2-naphthyl)-2,4,4-trimethyl-2,4-disilapentane. This result completes the revision of a previous report in which 1,8-bis(trimethylsilyl)naphthalene was claimed to undergo acid catalyzed rearrangement to the 1,7-isomer.
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