A series of optically active β-oxosulphoxides has been prepared and their reduction by metal hydrides examined; when lithium aluminium hydride is used, the extent of asymmetric synthesis is in the range 60-70%.
Asymmetric induction in the reduction of beta-oxosulphoxides by metal hydrides / R. Annunziata, M. Cinquini, F. Cozzi. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :7(1979), pp. 1687-1690.
Asymmetric induction in the reduction of beta-oxosulphoxides by metal hydrides
R. AnnunziataPrimo
;M. CinquiniSecondo
;F. CozziUltimo
1979
Abstract
A series of optically active β-oxosulphoxides has been prepared and their reduction by metal hydrides examined; when lithium aluminium hydride is used, the extent of asymmetric synthesis is in the range 60-70%.
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