The stereoselective construction of the D-erythro-azidosphingosine characteristic trans double bond was accomplished by condensation between tetradecanal and a heterocyclic sulfone derived from diethyl-D-tartrate, following the Kocienski modification of the Julia olefination.
A formal synthesis of 3-O-(4-methoxybenzyl)-azidosphingosine by a modified Julia olefination / F. Compostella, L. Franchini, L. Panza, D. Prosperi, F. Ronchetti. - In: TETRAHEDRON. - ISSN 0040-4020. - 58:22(2002), pp. 4425-4428.
A formal synthesis of 3-O-(4-methoxybenzyl)-azidosphingosine by a modified Julia olefination
F. Compostella;F. Ronchetti
2002
Abstract
The stereoselective construction of the D-erythro-azidosphingosine characteristic trans double bond was accomplished by condensation between tetradecanal and a heterocyclic sulfone derived from diethyl-D-tartrate, following the Kocienski modification of the Julia olefination.
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