To obtain water soluble transition-metal complexes, complexes obtained by reaction between [Ru(CO)3(PPh3)2] and dicarboxylic acids have been studied. The derivative obtained with oxalic acid, [Ru(O2CCO2H)2(CO)2(PPh3)2] (2), dissolves in water when treated with NEt3 and reacts with [Pt(PPh3)3] to give [Ru(CO)2(PPh3)2(μ-O2CCO2)2Pt(PPh3)2] (5).
Reactions of dicarboxylic acids with [Ru(CO)3(PPh3)2] / M. Pizzotti, S. Cenini, F. Porta. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 448:1-2(1993), pp. 205-209. [10.1016/0022-328X(93)80085-P]
Reactions of dicarboxylic acids with [Ru(CO)3(PPh3)2]
M. Pizzotti;S. Cenini;F. Porta
1993
Abstract
To obtain water soluble transition-metal complexes, complexes obtained by reaction between [Ru(CO)3(PPh3)2] and dicarboxylic acids have been studied. The derivative obtained with oxalic acid, [Ru(O2CCO2H)2(CO)2(PPh3)2] (2), dissolves in water when treated with NEt3 and reacts with [Pt(PPh3)3] to give [Ru(CO)2(PPh3)2(μ-O2CCO2)2Pt(PPh3)2] (5).
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