(24R)-[24-3H]- and (24S)-[24-3H]-cholesterols are transformed into tigogenin [(25R)-5α-spirostan-3β-ol] in Digitalis lanata without involvement of the hydrogen atoms at C-24; this confirms that the reduction of the Δ24-precursor of cholesterol is a ‘trans’ process.
Fate of C-24 hydrogen atoms of cholesterol during its conversion into tigogenin in Digitalis lanata / F. Ronchetti, G. Russo. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - :17(1976), pp. 1823-1825.
Fate of C-24 hydrogen atoms of cholesterol during its conversion into tigogenin in Digitalis lanata
F. RonchettiPrimo
;G. RussoUltimo
1976
Abstract
(24R)-[24-3H]- and (24S)-[24-3H]-cholesterols are transformed into tigogenin [(25R)-5α-spirostan-3β-ol] in Digitalis lanata without involvement of the hydrogen atoms at C-24; this confirms that the reduction of the Δ24-precursor of cholesterol is a ‘trans’ process.
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